catena-Poly[[bis(imidazole-N3)cadmium(II)]-bis(μ-thiocyanato)-S:N;N:S]

被引：25

作者：

Chen, HJ ^{[1
]}

Yang, G ^{[1
]}

Chen, XM ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199011075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title polymeric complex, [Cd(SCN)(2)(C3H4N2)(2)](n), exhibits an infinite chain structure in which each pair of Cd atoms is bridged by two eta-1,3-SCN- groups. The unique Cd atom lies on an inversion centre and the coordination sphere is completed by two imidazole N atoms to form a CdS2N4 octahedron. The polymeric chains are further extended into two-dimensional sheets via N-H ... S hydrogen bonds between the uncoordinated imidazole N atoms and the SCN- groups.

引用

页码：2012 / 2014

页数：3

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