Formation of inclusion organoactinide complexes with boron-containing macrocycles

被引：38

作者：

Barnea, E

Andrea, T

Kapon, M

Eisen, MS ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 16期

关键词：

D O I：

10.1021/ja0498843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the organoactinide complexes (C5Me5)2AnMe2 (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented. Copyright © 2003 American Chemical Society.

引用

页码：5066 / 5067

页数：2

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