Unusual fluorescent monomeric and dimeric dialkynyl dipyrromethene-borane complexes

被引:91
作者
Goze, Christine [1 ]
Ulrich, Gilles [1 ]
Ziessel, Raymond [1 ]
机构
[1] ECPM, CNRS, UMR 7509, Lab Chim Mol, F-67087 Strasbourg 02, France
关键词
D O I
10.1021/ol061601j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel monomeric and dimeric dialkynyl borondipyrromethene dyes (E-Bodipy) have been prepared in two different ways, providing systems in which the boron center is attached to either two similar or two dissimilar acetylenic units incorporating chromophores such as pyrene or anthracene. Both families exhibit interesting fluorescence and redox properties in which almost quantitative intramolecular energy transfer occurs.
引用
收藏
页码:4444 / 4448
页数:4
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