Oligocyanometallic cords as building blocks in luminescent three-dimensional coordination polymers:: [Ag4Cd2(tren)2(CN)6.5][Ag(CN)1.5] and [Au2Cd(tren)(CN)4]• H2O

被引：30

作者：

Zhang, H

Cai, JW ^{[1
]}

Feng, XL

Li, T

Li, XY

Ji, LN

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, State Key Lab Ultrafast Laser Spect, Guangzhou 510275, Peoples R China

[2] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 09期

基金：

中国国家自然科学基金;

关键词：

coordination polymers; luminescent emission; coinage metal; cyano;

D O I：

10.1016/S1387-7003(02)00514-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses, structures and luminescent properties of two unusual mixed-metal coordination polymers, namely [Ag4Cd2(tren)(2)(CN)(7,5)][Ag(CN)(1.5)] 1 and [AuCd(tren)(CN)(4)] . H2O 2 (tren = tris(2-aminoethyl)amine), are presented. Both compounds contain abnormal metal cords of oligocyanometallic anions as building blocks wherein the d(10)-d(10) interaction plays a crucial role in the metal-metal assembly. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：637 / 641

页数：5

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