Numerical investigation of the entropy crisis in model glass formers

被引:27
作者
Brumer, Y [1 ]
Reichman, DR [1 ]
机构
[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
D O I
10.1021/jp037617y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate numerically the low-temperature equilibration of glassy systems via nonlocal Monte Carlo methods. We reexamine several systems that have been studied previously and investigate new systems to test the performance of such methods near the putative Kauzmann temperature, T-K, where the configurational entropy is presumed to vanish. Our results suggest that previous numerical claims in favor of and against a thermodynamic transition at a finite T-K must be reevaluated. Our work provides some guidelines and suggestions for future numerical investigations of disordered systems at high densities and low temperatures.
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页码:6832 / 6837
页数:6
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