Principle of detailed balance in kinetics

被引：30

作者：

Alberty, RA ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF CHEMICAL EDUCATION | 2004年 / 81卷 / 08期

关键词：

D O I：

10.1021/ed081p1206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To clarify the application of the principle of detailed balance, calculations are performed on the interconversion of three isomers A, B, and C. The general case is represented by the chemical monomolecular triangle reaction. The three cases considered when A is initially present at 1 M are as follows: Case I: k1=k3=k5=1 and k2=k4=k6=0.

引用

页码：1206 / 1209

页数：4

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