Iridium and rhodium perfluorobenzenethiolato complexes. Syntheses and catalytic behavior

被引：7

作者：

Andrade, J

Garcia, JJ

Torrens, H

delRio, F

Claver, C

Ruiz, N

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,FAC QUIM,DEPT QUIM INORGAN,MEXICO CITY 04510,DF,MEXICO

[2] NATL AUTONOMOUS UNIV MEXICO,INST QUIM,MEXICO CITY 04510,DF,MEXICO

[3] UNIV ROVIRA & VIRGILI,FAC QUIM,TARRAGONA 43005,BARCELONA,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1997年 / 255卷 / 02期

关键词：

hydrogenation; hydroformylation; iridium complexes; rhodium complexes; pentamethylcyclopentadienyl complexes; thiolato complexes;

D O I：

10.1016/S0020-1693(96)05364-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reacting [(C5Me5)M(SRF)(2)] (for M = Ir, R-F = C6F5 (1a) or C6F4H-p (1b); for M = Rh, R-F = C6F5 (2a) or C6F4H-p (2b)) in toluene with L (L = CO and PPh3), mononuclear compounds with the general formula [(C5Me5)M(SRF)(2)(L)] (for M = Ir and L = CO, R-F = C6F5 (3a) or C6F4H-p (3b); for M = Ir and L = PPh3, R-F = C6F5 (4a) or C6F4H-p (4b); for M = Rh and L = CO, R-F = C6F5 (5a) or C6F4H-p (5b); for M = Rh and L = PPh3, R-F = C6F5 (6a) or C6F4H-p (6b)) can be obtained. The [(C5Me5)M(SRF)(2)] 1a and 1b systems have been studied as catalyst precursors for the hydrogenation of cyclohexene in 2-propanol at 5 and 30 bar at 40 degrees C; 2a and 2b systems were studied in the presence of PPh3 as catalyst precursors for the hydroformylation of 1-hexene in toluene at 5 and 30 bar at 80 degrees C.

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页码：389 / 393

页数：5

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