On the collapse of locally isostatic networks

被引:46
作者
Kapko, V. [1 ]
Treacy, M. M. J. [1 ]
Thorpe, M. F. [1 ]
Guest, S. D. [2 ]
机构
[1] Arizona State Univ, Dept Phys & Astron, Tempe, AZ 85287 USA
[2] Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
来源
PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2009年 / 465卷 / 2111期
基金
美国国家科学基金会;
关键词
flexibility; locally isostatic networks; zeolites; PERIODIC TETRAHEDRAL FRAMEWORKS; GENERIC RIGIDITY PERCOLATION; ENUMERATION; ZEOLITES; GRAPHS; MODES;
D O I
10.1098/rspa.2009.0307
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
070301 [无机化学]; 070403 [天体物理学]; 070507 [自然资源与国土空间规划学]; 090105 [作物生产系统与生态工程];
摘要
We examine the flexibility of periodic planar networks built from rigid corner-connected equilateral triangles. Such systems are locally isostatic, since for each triangle the total number of degrees of freedom equals the total number of constraints. These nets are two-dimensional analogues of zeolite frameworks, which are periodic assemblies of corner-sharing tetrahedra. If the corner connections are permitted to rotate, as if pin-jointed, there is always at least one collapse mechanism in two dimensions (and at least three mechanisms in three dimensions). We present a number of examples of such collapse modes for different topologies of triangular net. We show that the number of collapse mechanisms grows with the size of unit cell. The collapsible mechanisms that preserve higher symmetry of the network tend to exhibit the widest range of densities without sterical overlap.
引用
收藏
页码:3517 / 3530
页数:14
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