Low-threshold blue amplified spontaneous emission in a statistical copolymer and its blend

被引:32
作者
Lee, TW
Park, OO
Choi, DH
Cho, HN
Kim, YC
机构
[1] Korea Inst Sci & Technol, Polymer Mat Lab, Seoul 130650, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea
[3] Kyung Hee Univ, Coll Environm & Appl Chem, Inst Nat Sci, Mat Ctr Informat Display, Yongin 449701, Kyungki, South Korea
关键词
D O I
10.1063/1.1491297
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report low-threshold, blue amplified spontaneous emission (ASE) in a statistical copolymer, poly(9,9-dihexylfluorene-2,7-divinylene-m-phenylenevinylene-stat-p-phenylenevinylene) (CPDHFPV) and its blend with poly(9-vinylcarbazole) (PVK). PVK and CPDHFPV acted as the donor and the acceptor of the Forster-type excitation energy transfer, respectively. A single component waveguide made of CPDHFPV gave the threshold energy of 160 nJ/cm(2)/pulse. Moreover, that of the PVK/CPDHFPV (95/5 by wt.) blend device was as low as 20 nJ/cm(2)/pulse. From the relationship between the ASE intensity and the film thickness, we suggest that the optimum thickness for the photopumped ASE should be the transverse electric-mode cutoff thickness. (C) 2002 American Institute of Physics.
引用
收藏
页码:424 / 426
页数:3
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