(Acetonitrile)[2,6-bis(pyrazol-1-yl)-pyridine](isonicotinamide)copper(II)-tetrafluoroborate-acetonitrile (1/2/2)

被引:13
作者
Baum, G
Blake, AJ
Fenske, D
Hubberstey, P
Julio, C
Withersby, MA
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷
关键词
D O I
10.1107/S0108270102018097
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Molecules of the title compound, [Cu(C2H3N)(C11H9N5)-(C6H6N2O)](BF4)(2).2C(2)H(3)N, comprise (acetonitrile)[2,6-bis-(pyrazol-1-yl)pyridine](isonicotinamide)copper(II) cations, tetrafluoroborate anions and lattice acetonitrile molecules. The cations have distorted square-pyramidal geometries in which the N-3-donor, viz. 2,6-bis(pyrazol-1-yl)pyridine, and the N-donor, viz. the isonicotinamide ligand, occupy the four basal positions, with the coordinated acetonitrile N-donor atom occupying the apical position. Pairs of cations are linked by N-H...F hydrogen bonds through tetrafluoroborate anions, forming centrosymmetric dimers, which are further linked by C-H...O hydrogen bonds into two-dimensional undulating sheets, three of which interpenetrate to generate a two-dimensional network.
引用
收藏
页码:m542 / m544
页数:3
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