A molecular-beam Fourier transform microwave study of difluoromethane dimer

被引：41

作者：

Blanco, S ^{[1
]}

López, JC ^{[1
]}

Lesarri, A ^{[1
]}

Alonso, JL ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, Dept Quim Fis, E-47005 Valladolid, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2002年 / 612卷 / 2-3期

关键词：

molecular beam; molecular-beam Fourier transform microwave; hydrogen bond; molecular complexes; molecular structure;

D O I：

10.1016/S0022-2860(02)00096-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Difluoromethane dimer has been generated in a supersonic beam expansion and characterised using Fourier transform microwave spectroscopy. The rotational transitions of the parent species together with the spectra corresponding to both C-13 isotopomers have been measured. Spectral analysis yielded rotational and centrifugal distortion constants for the observed species. The r(0) and r(s) hydrogen-bond structural parameters of the complex were determined from the inertial data. The derived structure is consistent with a cooperative union in the dimer formed by three hydrogen bonds. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：255 / 260

页数：6

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