Enzymatic mediated polymerization of functional aniline derivatives in nonaqueous media

被引：12

作者：

AriasMarin, E

Romero, J

LedezmaPerez, A

Kniajansky, S

机构：

[1] CTR INVEST QUIM APLICADA,DEPT BIOPOLIMEROS,SALTILLO 25100,COAHUILA,MEXICO

[2] CTR INVEST QUIM APLICADA,DEPT QUIM POLIMEROS,SALTILLO 25100,COAHUILA,MEXICO

来源：

POLYMER BULLETIN | 1996年 / 37卷 / 05期

关键词：

D O I：

10.1007/BF00296602

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Horseradish peroxidase (HRP) catalyzed H2O2-dependent oxidation and polymerization of p-aminophenylmethycarbinol (pAPMC), but not p-aminoacetophenone (pAAP) or other aniline derivative with electron-withdrawing character. The effect of the H2O2 feed ratio on the polymerization was examined. Chemical structure was determined by IR and H-1, C-13 NMR spectroscopic analysis. The p(pAMPC) formed primarily through a covalent bond between the benzilic carbons and the amino group of another pAPMC molecule. Thermal stability of p(pAPMC) was analyzed by DSC and TGA.

引用

页码：581 / 587

页数：7

共 7 条

[1]

AKKARA JA, 1992, INDIAN J CHEM B, V31, P855

[2]

AKKARA JA, 1991, J POLYM SCI POL CHEM, V29, P561

[3]

[Anonymous], 1985, ADV ORG CHEM

[4]

ARIASMARIN E, 1996, MACROMOL REPORT A S3, V33, P229