anti,mer-[bis(2-diphenylphosphinoethyl)-(n-propyl)amine-N,P,P'](phenylethynyl)-[(Z)-1-p-tolyl-4-phenyl-eta(3)-but-1-en-3-ynyl]-ruthenium(II) chloroform solvate

被引：4

作者：

Bianchini, C

Masi, D

Peruzzini, M

Romerosa, A

Zanobini, F

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196002776

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title structure, [Ru(C8H5)(C17H13)(C31H35NP2)].CHCl3, consists of discrete anti,mer-[Ru(C=CPh){eta(3)PhC=C-C=CH(p-tolyl)}(PNP)] neutral molecules, where PNP is CH3CH2CH2N(CH(2)CH(2)PPh(2))(2), and CHCl3 solvate molecules. The Ru-II metal centre is pseudo-octahedrally coordinated by a meridional tridentate PNP ligand, a phenylethynyl ligand and a eta(3)-bonded (Z)-1-p-tolyl-4-phenyl-eta(3)-but-1-en-3-ynyl ligand. The butenynyl moiety is anti with respect to the n-propyl tail on the N-atom donor of the amino-diphosphine ligand and lies in a plane almost perpendicular to that containing the Ru(PNP) moiety.

引用

页码：1973 / 1976

页数：4

共 13 条

[1] DIYNE COORDINATION CHEMISTRY .4. SYNTHESIS, MOLECULAR-STRUCTURE, AND PROTONATION REACTIONS OF THE ZEROVALENT COMPLEX [RU(ETA-2-PHCC-CCPH)(CO)2(PPH3)2] [J].