Carbon degassing from the lithosphere

So far, the role of present-day Earth degassing in global C budget and climate effects has been focused to volcanic emissions. The non-volcanic escape of CO2-CH4 from the upper mantle, from carbonate bearing rocks in the crust, from hydrocarbon accumulations and from surface deposits and processes is here discussed in detail. An inventory of recent available data is presented. For the first time, a so large quantity of data is considered altogether showing clearly that the geological flux of carbon was previously significantly underestimated. Several lines of evidence show that non-volcanic C fluxes in "colder" environments are much greater than generally assumed. Local and regional data suggest that metamorphic decarbonation, hydrocarbon leakage and mud volcanoes could be significant CO2-CH4 sources at global scale. Moreover, extensive surface gas-geochemical observations, including soil-atmosphere flux investigations, open the possibility that ecosystems controlled by biogenic activity (soil, permafrost, seawater) can host important components of endogenous C gas (geogas), even in the absence of surface gas manifestations. This would imply the existence of a geological diffuse, background emission over large areas of our planet, New theories concerning the occurrence of pervasive geogas and lithospheric processes of C-gas production ("lithospheric loss in rigidity") can be taken as novel reference and rationale for re-evaluating geological sources of CO2 and CH4, and an important endeavour and work prospect for the years to come. Our survey shows that it is still very hard to arrive at a meaningful estimate of the lithospheric non-volcanic degassing into the atmosphere. Orders of 10(2)-10(3) Mt CO2/year can be provisionally considered. Assuming as lower limit for a global subaerial volcanic degassing 300 Mt/year, the lithosphere may emit directly into the atmosphere at least 600 Mt CO2/year (about 10% of the C source due to deforestation and land-use exchange), an estimate we still consider conservative. It is likely that temporal variations of lithosphere degassing, at Quaternary and secular scale, may influence the atmospheric C budget. The present-day lithosphere degassing would seem higher than the value considered to balance at Ma time-scale the CO2 uptake due to silicate weathering. (C) 2002 Elsevier Science B.V. All rights reserved.