Analytical solutions for spin 3/2 off-resonance line intensities in solid state NMR

被引：9

作者：

Ageev, SZ

Sanctuary, BC

机构：

[1] Department of Chemistry, McGill University, Montreal

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 255卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(96)00334-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The density matrix of a spin 3/2 subject to a first-order quadrupole interaction in solids and excited by an off-resonance rf pulse, is calculated analytically using the algebraic computer program MAPLE. The results are valid for arbitrary values of the rf amplitude, omega(1), quadrupolar coupling, omega(Q), and offset, Delta omega, and applied to the analysis of cases where the offset term is not negligible. The treatment can be readily modified to include a second-order quadrupolar interaction during the pulse.

引用

页码：71 / 78

页数：8

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