Nucleation and growth of anisotropic grain in block copolymers near order-disorder transition

被引:62
作者
Hashimoto, T [1 ]
Sakamoto, N [1 ]
Koga, T [1 ]
机构
[1] KYOTO UNIV,DEPT POLYMER CHEM,GRAD SCH ENGN,KYOTO 60601,JAPAN
来源
PHYSICAL REVIEW E | 1996年 / 54卷 / 05期
关键词
D O I
10.1103/PhysRevE.54.5832
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Ordering processes of a nearly symmetric block copolymer of polystyrene-block-polyisoprene quenched from the disordered state to the ordered state very close to the order-disorder transition temperature were lamellae developed in a disordered matrix and the shape of the grain was anisotropic, whose size along the lamellar normals is much larger than that parallel to the lamellar interfaces. This property was confirmed by the computer simulation of a phenomenological model.
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页码:5832 / 5835
页数:4
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