Surface properties of supported metallic clusters as determined by microcalorimetry of CO chemisorption

被引:31
作者
Guerrero-Ruiz, A
Maroto-Valiente, A
Cerro-Alarcón, M
Bachiller-Baeza, B
Rodríguez-Ramos, I
机构
[1] Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan & Tecn, Madrid 28040, Spain
[2] CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain
关键词
CO adsorption; microcalorimetry; supported metals; particle size; pretreatment;
D O I
10.1023/A:1015388812589
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Recent results achieved by microcalorimetry of CO adsorption over supported metal catalysts will be reviewed by considering some parameters that control the surface properties of the supported metallic particles. In particular, the effects induced by the nature and the particle size of supported metallic clusters, the conditions of pretreatment, the support materials, the addition of promoters and the presence of a second metal will be shown.
引用
收藏
页码:303 / 311
页数:9
相关论文
共 35 条
[1]  
ANDERSEN PJ, 1994, CATALYSIS, V11, P441
[2]  
AUROUX A, 1994, CATALYST CHARACTERIZ, P611
[3]   Interaction of carbon dioxide with the surface of zirconia polymorphs [J].
Bachiller-Baeza, B ;
Rodriguez-Ramos, I ;
Guerrero-Ruiz, A .
LANGMUIR, 1998, 14 (13) :3556-3564
[4]   Hydrogenation of citral on activated carbon and high-surface-area graphite-supported ruthenium catalysts modified with iron [J].
Bachiller-Baeza, B ;
Guerrero-Ruiz, A ;
Wang, P ;
Rodríguez-Ramos, I .
JOURNAL OF CATALYSIS, 2001, 204 (02) :450-459
[5]   INTERACTION BETWEEN ZEOLITES AND CLUSTER COMPOUNDS .1. ADSORPTION OF IRON PENTACARBONYL ON ZEOLITES [J].
BEIN, T ;
JACOBS, PA .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :1819-1831
[6]  
CARMONAMARTINEZ N, 1992, ADV CATAL, V38, P149
[7]   ADSORPTION OF CO ON PD SINGLE-CRYSTAL SURFACES [J].
CONRAD, H ;
ERTL, G ;
KOCH, J ;
LATTA, EE .
SURFACE SCIENCE, 1974, 43 (02) :462-480
[8]   MICROCALORIMETRIC, SPECTROSCOPIC, AND KINETIC-STUDIES OF SILICA-SUPPORTED PT AND PT/SN CATALYSTS FOR ISOBUTANE DEHYDROGENATION [J].
CORTRIGHT, RD ;
DUMESIC, JA .
JOURNAL OF CATALYSIS, 1994, 148 (02) :771-778
[9]  
Cotton F.A., 1998, ADV INORGANIC CHEM
[10]  
CRUCQ A, 1989, CATAL TODAY, V5, P223