The structure of bis(trimethylammonium) undecachlorotriantimonate(III) [(CH3)3NH]2Sb3Cl11 containing a novel antimony(III) anion

被引:3
作者
Bujak, M [1 ]
Zaleski, J [1 ]
机构
[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland
关键词
alkylammonium chloroantimonates(III); hydrogen bonds; disorder; lone electron pair; crystal structure;
D O I
10.1023/A:1009592618124
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The structure of [(CH3)(3)NH](2)Sb3Cl11 (space group P2(1)/n; a = 10.374(2) b = 23.723(5), c = 11.884(2) Angstrom, beta = 113.46(3)degrees; V = 2682.9(9) Angstrom(3)) consists of a structurally novel [Sb3Cl112-] anion and two crystallographically nonequivalent trimethylammonium cations. There are three deformed octahedra in the asymmetric part of the unit cell. They are connected with each other by edges and corners forming a characteristic polyanionic layer. Trimethylammonium cations, one ordered and one disordered, are connected to the inorganic sublattice by N-H ... Cl hydrogen bonds.
引用
收藏
页码:555 / 560
页数:6
相关论文
共 17 条
  • [1] Bator G., 1993, Ferroelectrics, V141, P177, DOI 10.1080/00150199308223445
  • [2] Bujak M, 1999, POL J CHEM, V73, P773
  • [3] Bis(dimethylammonium) pentachloroantimonate(III), on the deformation of the octahedral coordination of SbIII
    Bujak, M
    Zaleski, J
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1773 - 1777
  • [4] Chaabouni S, 1997, J CHEM CRYSTALLOGR, V27, P401
  • [5] ENSINGER U, 1982, Z NATURFORSCH B, V37, P1584
  • [6] HIGH-FREQUENCY DIELECTRIC-DISPERSION IN [(CH3)3NH]3SB2CL9
    JAKUBAS, R
    NAREWSKI, E
    SOBCZYK, L
    [J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1986, 98 (02): : K115 - K118
  • [7] TRIS(TRIMETHYLAMMONIUM) NONACHLORODIANTIMONATE(III), [NH(CH3)3]3[SB2CL9]
    KALLEL, A
    BATS, JW
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (JUL) : 1022 - 1024
  • [8] DIMETHYLAMMONIUM CHLOROANTIMONATES - STRUCTURE AND VIBRATIONAL-SPECTRA
    KNODLER, F
    ENSINGER, U
    SCHWARZ, W
    SCHMIDT, A
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 557 (02): : 208 - 218
  • [9] *KUM, 1996, KUM DIFFR SOFTW VERS
  • [10] Pauling L., 1960, NATURE CHEM BOND