The structure of bis(trimethylammonium) undecachlorotriantimonate(III) [(CH3)3NH]2Sb3Cl11 containing a novel antimony(III) anion

被引：3

作者：

Bujak, M ^{[1
]}

Zaleski, J ^{[1
]}

机构：

[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 05期

关键词：

alkylammonium chloroantimonates(III); hydrogen bonds; disorder; lone electron pair; crystal structure;

D O I：

10.1023/A:1009592618124

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of [(CH3)(3)NH](2)Sb3Cl11 (space group P2(1)/n; a = 10.374(2) b = 23.723(5), c = 11.884(2) Angstrom, beta = 113.46(3)degrees; V = 2682.9(9) Angstrom(3)) consists of a structurally novel [Sb3Cl112-] anion and two crystallographically nonequivalent trimethylammonium cations. There are three deformed octahedra in the asymmetric part of the unit cell. They are connected with each other by edges and corners forming a characteristic polyanionic layer. Trimethylammonium cations, one ordered and one disordered, are connected to the inorganic sublattice by N-H ... Cl hydrogen bonds.

引用

页码：555 / 560

页数：6

共 17 条

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