Polymer-supported N-heterocyclic carbene-rhodium complex catalyst for the addition of arylboronic acids to aldehydes

被引：28

作者：

Yan, Chun ^{[1
]}

Zeng, Xiaoming ^{[1
]}

Zhang, Weifeng ^{[1
]}

Luo, Meiming ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Sichuan 610064, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 15期

关键词：

N-heterocylic carbene-rhodium complex; polymeric support; heterogeneous catalyst; rhodium; arylation;

D O I：

10.1016/j.jorganchem.2006.02.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel polymer-supported N-heterocylic carbene (NHC)-rhodium complex was prepared from chloromethyl polystyrene (CM PS) resin using a simple procedure. This polymer-supported NHC-rhodium complex was used as a catalyst for the addition of arylboronic acids to aldehydes affording arylmethanols in excellent yields. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3391 / 3396

页数：6

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[1] Bromine-magnesium-exchange as a general tool for the preparation of polyfunctional aryl and heteroaryl magnesium-reagents [J].