Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

被引:126
作者
Hefter, G [1 ]
Marcus, Y [1 ]
Waghorne, WE [1 ]
机构
[1] Murdoch Univ, Chem Dept, Murdoch, WA 6150, Australia
关键词
D O I
10.1021/cr010031s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A wide-ranging critically evaluated compilation of the standard molar enthalpies and entropies of transfer of electrolytes from water to mixed aqueous-organic solvents were shown. For this compilation, the reported values were recalculated to obtain a consistent format that enabled comparisons to be made among the data. These whole-salt data were then split into the transfer functions of the individual ions, using an appropriate extrathermodynamic assumption.
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页码:2773 / 2835
页数:63
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