Hydrogen adsorption and desorption by carbon materials

被引：66

作者：

Kojima, Yoshitsugu ^{[1
]}

Kawai, Yasuaki

Koiwai, Akihiko

Suzuki, Nobuaki

Haga, Tetstuya

Hioki, Tatsumi

Tange, Kyoichi

机构：

[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

[2] Toyota Motor Co Ltd, Mat Engn Div 3, Shizuoka 4101193, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 421卷 / 1-2期

关键词：

hydrogen absorbing materials; gas-solid reaction; transmisson electron microscopy; thermodynamic properties; high-pressure;

D O I：

10.1016/j.jallcom.2005.09.077

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen adsorption and desorption in different carbon materials were determined at 77 and 296 K. Superactivated carbon having specific surface area of 3220 m(2)/g, adsorbed and desorbed 5 wt.% of hydrogen at 77 K and 1.3 wt.% of hydrogen at 296 K. The values were greater than those of conventional activated carbon, graphite nanofiber and single-walled carbon nanotube. The hydrogen adsorption capacities of the various carbon materials were given as a function of the specific surface area. According to the Clausius-Clapeyron equation, the heat of adsorption of the superactivated carbon was about 6 kJ/mol H-2. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：204 / 208

页数：5

共 38 条

[1] Hydrogen desorption and adsorption measurements on graphite nanofibers [J].

Ahn, CC ;

Ye, Y ;

Ratnakumar, BV ;

Witham, C ;

Bowman, RC ;

Fultz, B .

APPLIED PHYSICS LETTERS, 1998, 73 (23) :3378-3380

[2] HYDROGEN STORAGE ON SUPERACTIVATED CARBON AT REFRIGERATION TEMPERATURES [J].

AMANKWAH, KAG ;

NOH, JS ;

SCHWARZ, JA .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1989, 14 (07) :437-447

[3] An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst [J].

Amendola, SC ;

Sharp-Goldman, SL ;

Janjua, MS ;

Kelly, MT ;

Petillo, PJ ;

Binder, M .

JOURNAL OF POWER SOURCES, 2000, 85 (02) :186-189

[4]

Bénard P, 1998, HYDROGEN ENERGY PROGRESS XII, VOLS 1-3, P1121

[5] Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials [J].

Bogdanovic, B ;

Schwickardi, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 (1-2) :1-9

[6] LOW-PRESSURE ADSORPTION STORAGE OF HYDROGEN [J].

CHAHINE, R ;

BOSE, TK .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1994, 19 (02) :161-164

[7] Hydrogen storage in graphite nanofibers [J].

Chambers, A ;

Park, C ;

Baker, RTK ;

Rodriguez, NM .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (22) :4253-4256

[8] Interaction of hydrogen with metal nitrides and imides [J].

Chen, P ;

Xiong, ZT ;

Luo, JZ ;

Lin, JY ;

Tan, KL .

NATURE, 2002, 420 (6913) :302-304

[9] Storage of hydrogen in single-walled carbon nanotubes [J].

Dillon, AC ;

Jones, KM ;

Bekkedahl, TA ;

Kiang, CH ;

Bethune, DS ;

Heben, MJ .

NATURE, 1997, 386 (6623) :377-379

[10] Nanocrystalline aluminium hydrides for hydrogen storage [J].

Fichtner, M ;

Engel, J ;

Fuhr, O ;

Kircher, O ;

Rubner, O .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 108 (1-2) :42-47

← 1 2 3 4 →