Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(II) complexes

被引：270

作者：

Miyaura, N ^{[1
]}

机构：

[1] Hokkaido Univ, Dept Mol Chem, Fac Engn, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 653卷 / 1-2期

关键词：

cross-coupling; organoboron compounds; palladium(II) complexes;

D O I：

10.1016/S0022-328X(02)01264-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Until recently, organoboronic acids have been of limited use in organic synthesis due to their low reactivity for ionic reactions. During the past two decades; however, it has become increasingly clear that they are valuable reagents capable of undergoing many carbon-carbon bond formations in organic syntheses. In 1979, catalytic carbon-carbon bond formation, via transmetalation between organoboron compounds and palladium(II) halides, was found to proceed in the presence of a base. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：54 / 57

页数：4

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