Time-Resolved In Situ Synchrotron X-ray Study and Large-Scale Production of Magnetite Nanoparticles in Supercritical Water

被引：76

作者：

Bremholm, Martin

Felicissimo, Marcella

Iversen, Bo B. ^{[1
]}

机构：

[1] Univ Aarhus, Dept Chem, Ctr Energy Mat, DK-8000 Aarhus C, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 26期

关键词：

crystal growth; magnetite; nanostructures; supercritical fluids; X-ray diffraction; HYDROTHERMAL CRYSTALLIZATION; SIZE; PARTICLES; NANOCRYSTALS; TRANSITIONS; FLUIDS; CELLS;

D O I：

10.1002/anie.200901048

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general solution: In situ synchrotron X-ray scattering in a high-pressure pulsed injection reactor (see picture) shows that magnetite nucleation and growth are temporally separated. Gram-scale crystalline, pure phase, superparamagnetic magnetite nanoparticles were synthesized without surfactants in supercritical water in less than one hour using a laboratoryscale continuous-flow reactor. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

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页码：4788 / 4791

页数：4

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