Progress in polymerization of cyclic esters: Mechanisms and synthetic applications

被引：75

作者：

Biela, Tadeusz ^{[1
]}

Kowalski, Adam ^{[1
]}

Libiszowski, Jan ^{[1
]}

Duda, Andrzej ^{[1
]}

Penczek, Stanislaw ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Polymer Chem, PL-90363 Lodz, Poland

来源：

MACROMOLECULAR SYMPOSIA | 2006年 / 240卷

关键词：

aliphatic polyesters; controlled polymerization; epsilon-caprolactone; lacticles; star polymers;

D O I：

10.1002/masy.200650807

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recent advances in the controlled ring-opening polymerization of aliphatic cyclic esters are briefly reviewed. Particular attention is paid to the high molecular weight linear, branched, and star-shaped poly(lactide)s and poly(F-caprolactone) synthesis. It is concluded that despite the plethora of initiating and/or catalytic systems applied for this purpose the best results so far were achieved with Al- and Sn(II) derivatives. Analytical methods employed for aliphatic polyesters of various architectures characterization, including SEC-MALLS, LC-CC, and fluorescence spectroscopy, are also discussed.

引用

页码：47 / 55

页数：9

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