Preparation and study of properties of polymer electrolyte system (PEO+ NaClO3)

被引：36

作者：

Kumar, J. Siva ^{[1
]}

Subrahmanyam, A. R. ^{[1
]}

Reddy, M. Jaipal ^{[1
]}

Rao, U. V. Subba ^{[1
]}

机构：

[1] Osmania Univ, Dept Phys, Hyderabad 500007, Andhra Pradesh, India

来源：

MATERIALS LETTERS | 2006年 / 60卷 / 28期

关键词：

polymer electrolyte; poly(ethylene oxide); NaClO3; ionic conductivity; transference numbers; electrochemical cell;

D O I：

10.1016/j.matlet.2006.03.015

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A polymer electrolyte based on PEO complexed with sodium salt (NaClO3) has been prepared by a solution-cast technique. Various properties such as the composition-dependence conductivity, temperature-dependence conductivity in the temperature range of 303-373 K and the transference number measurements have been carried out to characterize the polymer electrolyte system. The conductivity of the electrolyte (PEO + NaClO3) is about 103 times larger than that of pure PEO at room temperature. The transport number measurements show that the charge transport is mainly due to ions in this polymer electrolyte system. An electrochemical cell with the configuration Na/(PEO + NaClO3)/(I-2 + C + electrolyte) has been fabricated and its discharge characteristics were studied. The Open Circuit Voltage (OCV) and Short Circuit Current (SCC) are 2.97 V and 346 mu A, respectively. Other parameters of the cell are evaluated and presented in this paper. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3346 / 3349

页数：4

共 31 条

[1] POLYMER ELECTROLYTES [J].

ARMAND, MB .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :245-261

[2]

CHANDRA S, 1990, SOLID STATE IONICS, V40, P632

[3]

CHERADAME H, 1989, FARADAY DISCUSS, V88, P77

[4] GENERALIZED HOPPING MODEL FOR FREQUENCY-DEPENDENT TRANSPORT IN A DYNAMICALLY DISORDERED MEDIUM, WITH APPLICATIONS TO POLYMER SOLID ELECTROLYTES [J].

DRUGER, SD ;

RATNER, MA ;

NITZAN, A .

PHYSICAL REVIEW B, 1985, 31 (06) :3939-3947

[5] DYNAMIC BOND PERCOLATION THEORY - A MICROSCOPIC MODEL FOR DIFFUSION IN DYNAMICALLY DISORDERED-SYSTEMS .1. DEFINITION AND ONE-DIMENSIONAL CASE [J].

DRUGER, SD ;

NITZAN, A ;

RATNER, MA .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (06) :3133-3142

[6]

FANTEUX D, 1986, J ELECTROCHEM SOC, V133, P307

[7] PROTON-CONDUCTING POLYMER ELECTROLYTE .1. THE POLYETHYLENE OXIDE + NH4CIO4 SYSTEM [J].

HASHMI, SA ;

KUMAR, A ;

MAURYA, KK ;

CHANDRA, S .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1990, 23 (10) :1307-1314

[8] Study of transport and electrochemical cell characteristics of PVP:NaClO3polymer electrolyte system [J].

Kumar, KN ;

Sreekanth, T ;

Reddy, MJ ;

Rao, UVS .

JOURNAL OF POWER SOURCES, 2001, 101 (01) :130-133

[9] PHASE-DIAGRAMS AND CONDUCTIVITY BEHAVIOR OF POLY(ETHYLENE OXIDE) MOLTEN-SALT RUBBERY ELECTROLYTES [J].

LASCAUD, S ;

PERRIER, M ;

VALLEE, A ;

BESNER, S ;

PRUDHOMME, J ;

ARMAND, M .

MACROMOLECULES, 1994, 27 (25) :7469-7477

[10] PHASE-BEHAVIOR AND CONDUCTIVITY IN POLY(ETHYLENE OXIDE)-SODIUM THIOCYANATE SYSTEMS [J].

LEE, YL ;

CRIST, B .

JOURNAL OF APPLIED PHYSICS, 1986, 60 (08) :2683-2689

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