Chemistry of the lanthanides using pyrazolylborate ligands

被引：245

作者：

Marques, N

Sella, A

Takats, J

机构：

[1] ITN, Dept Quim, P-2686953 Sacavem, Portugal

[2] UCL, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England

[3] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 06期

关键词：

D O I：

10.1021/cr010327y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isolation of well-defined molecular species often requires the use of sterically demanding ligands. As such, the pyrazolylborate ligands represent an attractive and versatile alternative. The facile manipulation of the 3- and 5-substituents of the pyrazolyl rings allows the fine-tuning of the ligand size and thereby implies the possibility of controlling the metal coordination sphere to an unprecedented degree. This paper updates the previous comprehensive review which covered both lanthanide and actinide chemistry.

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页码：2137 / 2159

页数：23

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