Refinement of the structure of β-U4O9

被引:71
作者
Cooper, RI [1 ]
Willis, BTM [1 ]
机构
[1] Univ Oxford, Oxford OX1 3TA, England
来源
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES | 2004年 / 60卷
关键词
D O I
10.1107/S010876730401219X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
beta-U4O9 is a superlattice structure based on the fluorite arrangement of UO2. The U atoms occupy positions close to those in UO2 and the additional O atoms are accommodated in cuboctahedral clusters of (4) over bar 3m symmetry, which are centred on the special 12-fold sites of the cubic space group I<(4)overbar>3d. The structure has been refined from single-crystal neutron data in accordance with the procedure described in the previous paper [Popa & Willis (2004). Acta Cryst. A60, 318-321].
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页码:322 / 325
页数:4
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