Nitrido-sodalite Zn-6[P12N24] as a material for reversible hydrogen encapsulation

被引：18

作者：

Weitkamp, J

Ernst, S

Cubero, F

Wester, F

Schnick, W

机构：

[1] UNIV BAYREUTH,ANORGAN CHEM LAB,D-95440 BAYREUTH,GERMANY

[2] UNIV STUTTGART,INST TECH CHEM 1,D-70550 STUTTGART,GERMANY

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 03期

关键词：

D O I：

10.1002/adma.19970090314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Host-guest behavior in a nitrido-sodalite is reported for the first time. The novel nitrido-sodalite Zn-6[P12N24] has the usual nitrido-sodalite structure with PN4 corner-sharing units, as shown in the Figure, except that the central anion and one quarter of the Zn2+ ions are absent, producing only partial filling of the beta-cages. Hydrogen encapsulation in the beta-cages is discussed.

引用

页码：247 / &

页数：3

共 11 条

[1] Self-assembling frameworks: Beyond microporous oxides [J].