The [bis(η5-cyclopentadienyl)titanium(IV)-bis(L-methionine)] dichloride

被引:7
作者
Bína, R
Císarová, I
Pavlista, M
Pavlík, I
机构
[1] Univ Pardubice, Res Ctr New Inorgan Cpds & Adv Mat, Pardubice 53210, Czech Republic
[2] Charles Univ, Fac Nat Sci, Prague 12843, Czech Republic
关键词
titanocene dichloride; alpha-amino acids;
D O I
10.1002/aoc.623
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The structure of ionic complex [Cp2Ti(L-Met)(2)](2+) [Cl-](2) (where Cp = eta(5)-C5H5) possessing C-2 symmetry is presented. Discrete cationic units with distorted tetrahedral geometry around the central titanium atom are connected through intermolecular (HCl)-Cl-... bonds between ammonium group protons of alpha-amino acid ligands and chloride anions. Copyright (C) 2004 John Wiley Sons, Ltd.
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页码:262 / 263
页数:2
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