Preparation and characterization of Cu2O/TiO2 nano-nano heterostructure photocatalysts

被引:170
作者
Huang, Lei [1 ,2 ]
Peng, Feng [1 ,2 ]
Wang, Hongjuan [1 ]
Yu, Hao [1 ]
Li, Zhong [1 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China
[2] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalysis; Heterostructure; Cuprous oxide; Visible light irradiation; Titania; TIO2; HETEROJUNCTIONS; DEGRADATION; PARTICLES; FILM;
D O I
10.1016/j.catcom.2009.06.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cu2O/TiO2 nano-nano heterostructures with different concentrations of Cu2O were prepared by an alcohol-aqueous based chemical precipitation method, and were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy and UV-vis diffuse reflection absorption spectra. The photocatalytic efficiency of the Cu2O/TiO2 heterostructures was evaluated by degradation of Acid Orange 11 in water under UV-vis light and visible light irradiation. The results show that the heterostructures have dramatically improved photocatalytic activity comparing with pure TiO2 (P25). The prepared Cu2O/TiO2 heterostructures with the Cu2O concentrations of 30% and 70% have the best photocatalytic efficiencies, which are 6 times and 27 times higher than that of pure TiO2 (P25) under UV-vis light and visible light irradiation, respectively. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1839 / 1843
页数:5
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