Ru(II)-bipyridine complexes in supramolecular systems, devices and machines

被引：255

作者：

Balzani, Vincenzo ^{[1
]}

Bergamini, Giacomo ^{[1
]}

Marchioni, Filippo ^{[1
]}

Ceroni, Paola ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 11-12期

关键词：

photochemistry; photophysics; electrochemistry; supramolecular chemistry; molecular devices; molecular machines;

D O I：

10.1016/j.ccr.2005.11.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Because of a unique combination of chemical stability, redox properties, excited-state reactivity, and excited-state lifetime, [Ru(bpy)(3)](2+) (bpy = 2,2'-bipyridine) and related complexes have long been used to obtain photoinduced intermolecular energy and electron-transfer processes. More recently these compounds have been employed as components to build up supramolecular species that exhibit peculiar photochemical and/or electrochemical properties. When suitably designed, such supramolecular species can behave as light-powered nanoscale electronic devices (e.g. wires, switches, antennas) or mechanical machines (e.g. shuttles). This paper reviews the results obtained in our research group on supramolecular species, devices and machines that exploit the properties of Ru(H) bipyridine complexes. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1254 / 1266

页数：13

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