An internal reformer for a pressurised SOFC system

被引:10
作者
Agnew, G. D.
Bernardi, D.
Collins, R. D.
Cunningham, R. H.
机构
[1] Rolls Royce Fuel Cell Syst Ltd, Loughborough LE11 3GR, Leics, England
[2] Univ Genoa, I-16145 Genoa, Italy
关键词
internal-reforming; kinetics; heat-transfer; catalyst;
D O I
10.1016/j.jpowsour.2005.11.101
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel reformer design has been demonstrated that converts the methane required for a multi kilowatt SOFC stack. Results show the influence of temperature and the benefits of operating at elevated pressure on the reforming-catalyst fundamental reaction kinetics. Due to the high heat demand of the steam reforming reaction, efficient heat transfer between the SOFC stack and the reforming catalyst is essential. Parameters such as the volume/surface area ratio, choice of catalyst, and catalyst metal loading are key to the design, and these have been determined through a combination of computer modelling and experimental measurements. The thermal properties of the unit have been evaluated over a range of temperatures and fuel compositions that simulate system operating-conditions in the final product. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:832 / 836
页数:5
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