Stable anisotropic films obtained by in-situ photopolymerization of discotic liquid crystalline acrylates

被引：54

作者：

FavreNicolin, CD

Lub, J

机构：

[1] Philips Research (WB 61), 5656 AA Eindhoven

来源：

MACROMOLECULES | 1996年 / 29卷 / 19期

关键词：

D O I：

10.1021/ma951818l

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New discotic liquid crystals with one, two, or three reactive acrylate end groups were synthesized. They exhibit a wide discotic nematic phase and show spontaneous homeotropic alignment between substrates. The photoinitiated polymerization of these materials was studied. ''In-situ photopolymerization'' of these disklike acrylates leads to transparent and thermally stable films with a negative birefringence.

引用

页码：6143 / 6149

页数：7

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