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Ligand-free Heck reactions using low Pd-loading

被引：653
作者：
Reetz, MT
de Vries, JG
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
[2] DSM Pharma Chem Adv Synth Catalysis & Dev, NL-6160 MD Geleen, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 14期
关键词：
D O I：
10.1039/b406719n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Activated and non-activated aryl bromides undergo smooth ligand-less Heck reactions, provided low amounts of palladium salts such as Pd(OAc)(2) are used (ideally 0.01-0.1 mol%). This industrially viable process appears to involve palladium nanoparticles.
引用
收藏
页码：1559 / 1563
页数：5
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