Synthesis of free and ruthenium coordinated 5,6-diamino-1,10-phenanthroline

被引：154

作者：

Bodige, S ^{[1
]}

MacDonnell, FM ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,ARLINGTON,TX 76019

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(97)10223-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new preparative route to 5,6-diamino-1, 10-phenanthroline is described which triples the isolated yields found in existing syntheses (67% vs. 22% from 1,10-phenanthroline) and utilizes mild reaction conditions. The method is general and can even be used on chiral metal complexes containing the appropriate starting material/ligand, 1,10-phenanthroline-5,6-dione, with retention of stereochemistry. (C) 1997 Elsevier Science Ltd.

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页码：8159 / 8160

页数：2

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