Effects of Anodization Growth of TiO2-Nanotube Array Membrane on Photo-conversion Efficiency of Dye-Sensitized Solar Cell

被引:23
作者
Park, Min-Woo [1 ]
Chun, Ki-Young [1 ]
机构
[1] Kyungsung Univ, Dept Mat Engn, Pusan 608736, South Korea
关键词
TiO2; nanotube; anodic oxidation; dye-sensitized solar cell; photo-conversion; TIO2 NANOTUBE ARRAYS; MU-M; LENGTH; FILMS;
D O I
10.3365/eml.2009.03.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Membranes of TiO2 nanotube(NT) arrays were grown by potentiostatic anodic oxidation in an ethylene glycol electrolyte with small addition Of H2O and NH4F. Ti metal plate with a thickness of 0.1 mm was completely converted into similar to 0.2 mm-thick TiO2 NT membrane for 24 to 96 h of anodization. Stacked NTs in membrane were separated into individual NT from the neighboring NTs as anodization continues up to 96 h. As-fabricated membrane of NTs were mechanically grinded to yield fine NT particles for the photoanode application to dye-sensitized solar cells (DSCs), in replacement of conventional TiO2 particles. Photo-conversion efficiency of the DSC using TiO2 crystalline NT particles is varying from 2.22% to 5.03%. Fine TiO2 NT particles can increase dye attachment due to high surface to volume ratio.
引用
收藏
页码:7 / 11
页数:5
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