Partial etherification reactions of cavitand phenol bowls

被引：7

作者：

Barrett, ES ^{[1
]}

Irwin, JL ^{[1
]}

Picker, K ^{[1
]}

Sherburn, MS ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 05期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH02031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions between the C-4v-symmetrical cavitand tetraphenol (2), various bases, and less than 4 molar equivalents of alkyl halides result in the generation of statistical mixtures of the five possible ether products along with unreacted starting material. Useful quantities of monoalkoxytriphenol (8), A,B-dialkoxydiphenol (9) and trialkoxymonophenol (11) are obtained by controlling the reaction stoichiometry and the desired products can, in general, be isolated by straightforward chromatographic means.

引用

页码：319 / 325

页数：7

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