Study of the nucleophilic reaction of 2-mercaptoethanol with 1-fluoroalkyl-2-iodo-alkenes

被引：6

作者：

Guan, HP ^{[1
]}

Luo, BH ^{[1
]}

Hu, CM ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1997年 / 85卷 / 02期

关键词：

1-fluoroalkyl-2-iodo-alkenes; 2-mercaptoethanol; nucleophilic reaction;

D O I：

10.1016/S0022-1139(97)00074-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stepwise nucleophilic addition of 2-mercaptoethanol (2) to 1-fluoroalkyl-2-iodo-alkenes (1) was studied. Fluorine-containing building blocks of a new type (4) containing a fluorine atom, a fluoroalkyl-substituted double bond and a latent carbonyl group were synthesized in good yield via the intermediate thioethers 3. A reasonable pathway is suggested. (C) 1997 Elsevier Science S.A.

引用

页码：141 / 145

页数：5

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