Multivalency in the gas phase: The study of dendritic aggregates by mass spectrometry

被引:54
作者
Broeren, MAC [1 ]
van Dongen, JLJ [1 ]
Pittelkow, M [1 ]
Christensen, JB [1 ]
van Genderen, MHP [1 ]
Meijer, EW [1 ]
机构
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
关键词
dendrimers; dynamic libraries; host-guest chemistry; mass spectrometry; supramolecular chemistry;
D O I
10.1002/anie.200453707
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selective guest ejection: Up to eight guest molecules are assembled at the periphery of a third-generation dendrimer. Collision-induced dissociation mass spectrometry has demonstrated that the guests are removed very selectively in a one-by-one manner (see spectrum).
引用
收藏
页码:3557 / 3562
页数:6
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