Applications of metathesis in heterogeneous catalysis and separation sciences

被引:17
作者
Buchmeiser, MR [1 ]
机构
[1] Univ Innsbruck, Inst Analyt Chem & Radiochem, A-6020 Innsbruck, Austria
关键词
metathesis; heterogeneous catalysis; separation science; life sciences;
D O I
10.1016/S1381-1169(02)00227-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
During the last 15 years, the area of well-defined metathesis initiator systems was characterized by almost dramatic improvements in terms of initiator activity, stability, and selectivity. In due consequence, control over polymer properties increased and metathesis-based polymerization techniques (in particular ring-opening metathesis polymerization, ROMP) have been adapted for materials science purposes. Quite recently, metathesis-based supports have entered the fields of heterogeneous catalysis as well as separation and life sciences. In this review, both the synthesis and properties of metathesis-based well-defined catalytic supports and separations systems shall be summarized. Special consideration will be given to the particular structural features that have been made possible using ROMP. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:145 / 158
页数:14
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