A rapid regioselective ring-opening of aziridines with potassium thiocyanate using ammonium-12-molybdophosphate

被引：16

作者：

Das, Biswanath ^{[1
]}

Reddy, V. Saidi ^{[1
]}

Ramu, R. ^{[1
]}

Kumar, D. Nandan ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

CATALYSIS COMMUNICATIONS | 2006年 / 7卷 / 12期

关键词：

aziridine; KSCN; (NH4)(3)[PMo12O40; beta-aminothiocyanate; regioselectivity;

D O I：

10.1016/j.catcom.2006.05.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonium-12-molybdophosphate, a heterogeneous catalyst, has been utilized for the first time for rapid (within 15-20 min) regioselective ring-opening of aziridines with KSCN at room temperature to form the corresponding beta-aminothiocyanates in high yields. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：997 / 999

页数：3

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