Infrared and visible Fourier-transform spectra of sulfuric-acid-water aerosols at 230 and 294 K

被引:15
作者
Heathfield, AE
Newnham, DA
Ballard, J
Grainger, RG
Lambert, A
机构
[1] Rutherford Appleton Lab, Dept Space Sci, Didcot OX11 0QX, Oxon, England
[2] Univ Oxford, Clarendon Lab, Dept Atmospher Ocean & Planetary Phys, Oxford OX1 3PU, England
关键词
D O I
10.1364/AO.38.006408
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The extinction spectra of aqueous sulfuric acid aerosols fully covering the mid-IR to visible regions from 750 to 23,000 cm(-1) (13.9-0.4 mu m) have been measured in the laboratory with a Fourier-transform spectrometer. Both large and small aerosol particles with compositions of approximately 60-70-wt.% H2SO4 were generated and their spectra recorded at 230 and 294 K. The spectra were fitted to a model incorporating roam-temperature refractive-index data [Appl. Opt. 14, 208 (1975)] and Mie theory calculations to characterize the composition and size distributions of the aerosol samples. (C) 1999 Optical Society of America.
引用
收藏
页码:6408 / 6420
页数:13
相关论文
共 31 条
[1]  
[Anonymous], IPCC CLIMATE CHANGE
[2]  
Ansmann A, 1997, J ATMOS SCI, V54, P2630, DOI 10.1175/1520-0469(1997)054<2630:EOTPAR>2.0.CO
[3]  
2
[4]   FTIR STUDIES OF LOW-TEMPERATURE SULFURIC-ACID AEROSOLS [J].
ANTHONY, SE ;
TISDALE, RT ;
DISSELKAMP, RS ;
TOLBERT, MA ;
WILSON, JC .
GEOPHYSICAL RESEARCH LETTERS, 1995, 22 (09) :1105-1108
[5]   Mechanisms and temperatures for the freezing of sulfuric acid aerosols measured by FTIR extinction spectroscopy [J].
Bertram, AK ;
Patterson, DD ;
Sloan, JJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (06) :2376-2383
[6]   Heterogeneous reactions on stratospheric background aerosols, volcanic sulfuric acid droplets, and type I polar stratospheric clouds: Effects of temperature fluctuations and differences in particle phase [J].
Borrmann, S ;
Solomon, S ;
Dye, JE ;
Baumgardner, D ;
Kelly, KK ;
Chan, KR .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D3) :3639-3648
[7]   COMPARATIVE OBSERVATIONS OF STRATOSPHERIC AEROSOLS BY GROUND-BASED LIDAR, BALLOON-BORNE POLARIMETER, AND SATELLITE SOLAR OCCULTATION [J].
BROGNIEZ, C ;
SANTER, R ;
DIALLO, BS ;
HERMAN, M ;
LENOBLE, J ;
JAGER, H .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D18) :20805-20823
[8]   Infrared spectroscopy of sulfuric acid water aerosols: Freezing characteristics [J].
Clapp, ML ;
Niedziela, RF ;
Richwine, LJ ;
Dransfield, T ;
Miller, RE ;
Worsnop, DR .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D7) :8899-8907
[9]   Observations of the impact of volcanic activity on stratospheric chemistry [J].
Coffey, MT .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1996, 101 (D3) :6767-6780
[10]   INSITU MEASUREMENTS CONSTRAINING THE ROLE OF SULFATE AEROSOLS IN MIDLATITUDE OZONE DEPLETION [J].
FAHEY, DW ;
KAWA, SR ;
WOODBRIDGE, EL ;
TIN, P ;
WILSON, JC ;
JONSSON, HH ;
DYE, JE ;
BAUMGARDNER, D ;
BORRMANN, S ;
TOOHEY, DW ;
AVALLONE, LM ;
PROFFITT, MH ;
MARGITAN, J ;
LOEWENSTEIN, M ;
PODOLSKE, JR ;
SALAWITCH, RJ ;
WOFSY, SC ;
KO, MKW ;
ANDERSON, DE ;
SCHOEBERL, MR ;
CHAN, KR .
NATURE, 1993, 363 (6429) :509-514