Hybrid electrochemical capacitors based on polyaniline and activated carbon electrodes

被引:214
作者
Park, JH [1 ]
Park, OO [1 ]
机构
[1] Korea Adv Inst Sci & Technol, CAFPoly, Dept Chem Engn, Yusong Gu, Taejon 305701, South Korea
关键词
supercapacitor; electrochemical capacitor; hybrid capacitor; energy storage;
D O I
10.1016/S0378-7753(02)00304-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance of a newly designed, polyaniline-activated carbon, hybrid electrochemical capacitor is evaluated. The capacitor is prepared by using polyaniline as a positive electrode and activated carbon as a negative electrode. From a constant charge-discharge test, a specific capacitance of 380 F g(-1) is obtained. The cycling behaviour of the hybrid electrochemical capacitor is examined in a two-electrode cell by means of cyclic voltammetry. The cycle-life is 4000 cycles. Values for the specific energy and specific power of 18 Wh kg(-1) and 1.25 kW kg(-1), respectively, are demonstrated for a cell voltage between 1 and 1.6 V. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:185 / 190
页数:6
相关论文
共 22 条
  • [1] Polypyrrole/polymer electrolyte composites prepared by in situ electropolymerization of pyrrole as cathode/electrolyte material for facile electron transfer at the solid interface
    Amanokura, J
    Suzuki, Y
    Imabayashi, S
    Watanabe, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (04) : D43 - D48
  • [2] An KH, 2001, ADV MATER, V13, P497, DOI 10.1002/1521-4095(200104)13:7<497::AID-ADMA497>3.0.CO
  • [3] 2-H
  • [4] Polymer-based redox supercapacitors: A comparative study
    Arbizzani, C
    Mastragostino, M
    Meneghello, L
    [J]. ELECTROCHIMICA ACTA, 1996, 41 (01) : 21 - 26
  • [5] Characterization and long-term performance of polyaniline-based electrochemical capacitors
    Bélanger, D
    Ren, XM
    Davey, J
    Uribe, F
    Gottesfeld, S
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) : 2923 - 2929
  • [6] DUPASQUIER A, 1996, P ELECTROCHEMISTRY S, V96, P25
  • [7] Physicochemical and electrochemical characterization of polycyclopenta[2,1-b;3,4-b′]dithiophen-4-one as an active electrode for electrochemical supercapacitors
    Fusalba, F
    El Mehdi, N
    Breau, L
    Bélanger, D
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (10) : 2743 - 2753
  • [8] Electrochemical characterization of polyaniline in nonaqueous electrolyte and its evaluation as electrode material for electrochemical supercapacitors
    Fusalba, F
    Gouérec, P
    Villers, D
    Bélanger, D
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) : A1 - A6
  • [9] The effect of nickel foam current collector in carbon electrode based electric double layer capacitor
    Kim, JH
    Shin, KH
    Jin, CS
    Kim, DK
    Kim, YG
    Park, JH
    Lee, YS
    Joo, YS
    Lee, KH
    [J]. ELECTROCHEMISTRY, 2001, 69 (11) : 853 - 857
  • [10] Electrochemical characteristics of LiMn2O4-polypyrrole composite cathode for lithium polymer batteries
    Kim, JU
    Jeong, IS
    Moon, SI
    Gu, HB
    [J]. JOURNAL OF POWER SOURCES, 2001, 97-8 : 450 - 453