Can La2-xSrxCuO4 be used as anodes for direct methanol fuel cells?

被引：35

作者：

Raghuveer, V ^{[1
]}

Viswanathan, B ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

FUEL | 2002年 / 81卷 / 17期

关键词：

direct methanol fuel cells; perovskite; anode electrocatalyst;

D O I：

10.1016/S0016-2361(02)00167-9

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Attempt has been made to obtain the relationship between the electrophysical and electrochemical properties in order to provide a possible basis for designing new electrode materials for fuel cell applications. The substituted lanthanum cuprates of composition La2-xMxCu1-yM'O-y(4) (where M = Sr, Ca and Ba; M' = Sb and Ru; 0.0 less than or equal to x less than or equal to 0.4 and y = 0.1) were used to demonstrate the correlation of the Fermi level and carrier concentration with the methanol oxidation onset potential and activity, respectively. The activity of bulk material is compared with that of the nanocrystalline material prepared by the polymer modified sol-gel method. The nanocrystalline material was characterized by TGA, XRD, SEM, TEM and cyclic voltammetry. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：2191 / 2197

页数：7

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