Formation of conjugated polymer brushes by surface-initiated catalyst-transfer polycondensation

被引:80
作者
Sontag, S. Kyle
Marshall, Nicholas
Locklin, Jason [1 ]
机构
[1] Univ Georgia, Dept Chem, Fac Engn, Athens, GA 30602 USA
关键词
CHAIN-GROWTH POLYMERIZATION; SUZUKI POLYCONDENSATION; COUPLING REACTION; NICKEL-COMPLEXES; POLYFLUORENE; MONOLAYERS; POLY(3-ALKYLTHIOPHENES); MECHANISM; BENZENE; FILMS;
D O I
10.1039/b907264k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electroactive conjugated polymer brushes of poly(thiophene) and poly(phenylene) have been prepared via a surface-initiated Kumada-type polycondensation reaction, yielding films with a thickness up to 42 nm.
引用
收藏
页码:3354 / 3356
页数:3
相关论文
共 23 条
[1]   Formation of polyphenylene films on metal electrodes by electrochemical reduction of benzenediazonium salts [J].
Adenier, A ;
Combellas, C ;
Kanoufi, F ;
Pinson, J ;
Podvorica, FI .
CHEMISTRY OF MATERIALS, 2006, 18 (08) :2021-2029
[2]   Synthesis, Optical, and Electronic Properties of Soluble Poly-p-phenylene Oligomers as Models for Molecular Wires [J].
Banerjee, Moloy ;
Shukla, Ruchi ;
Rathore, Rajendra .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1780-1786
[3]   Patterned polyfluorene surfaces by functionalization of nanoimprinted polymeric features [J].
Beinhoff, M ;
Appapillai, AT ;
Underwood, LD ;
Frommer, JE ;
Carter, KR .
LANGMUIR, 2006, 22 (06) :2411-2414
[4]   Grafting of Polyfluorene by Surface-Initiated Suzuki Polycondensation [J].
Beryozkina, Tetyana ;
Boyko, Ksenia ;
Khanduyeva, Natalya ;
Senkovskyy, Volodymyr ;
Horecha, Marta ;
Oertel, Ulrich ;
Simon, Frank ;
Stamm, Manfred ;
Kiriy, Anton .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (15) :2695-2698
[5]   Controlling the growth of conjugated polymers on electrode surface:: Synthesis, electropolymerization, and spectroelectrochemistry of conjugated bispyrroles [J].
Büschel, M ;
Ajayaghosh, A ;
Eldo, J ;
Daub, J .
MACROMOLECULES, 2002, 35 (22) :8405-8412
[6]   LOW POTENTIAL ANODIC POLYMERIZATION OF BENZENE IN STRONG ACID AND SUPERACID SOLUTIONS [J].
GOLDENBERG, LM ;
AEIYACH, S ;
LACAZE, PC .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 335 (1-2) :151-161
[7]   New convenient synthesis of highly regioregular poly(3-octylthiophene) based on the Suzuki coupling reaction [J].
Guillerez, S ;
Bidan, G .
SYNTHETIC METALS, 1998, 93 (02) :123-126
[8]   Experimental evidence for the quasi-"living" nature of the grignard metathesis method for the synthesis of regioregular poly(3-alkylthiophenes) [J].
Iovu, MC ;
Sheina, EE ;
Gil, RR ;
McCullough, RD .
MACROMOLECULES, 2005, 38 (21) :8649-8656
[9]   Mechanistic aspects of the Suzuki polycondensation of thiophenebisboronic derivatives and diiodobenzenes analyzed by MALDI-TOF mass spectrometry [J].
Jayakannan, M ;
van Dongen, JLJ ;
Janssen, RAJ .
MACROMOLECULES, 2001, 34 (16) :5386-5393
[10]   Disubstituted polyacetylene brushes grown via surface-directed tungsten-catalyzed polymerization [J].
Jhaveri, Sarav B. ;
Carter, Kenneth R. .
LANGMUIR, 2007, 23 (16) :8288-8290