Low temperature synthesis of high molecular weight polyaniline using dichromate oxidant.

被引：37

作者：

Adams, PN ^{[1
]}

Abell, L ^{[1
]}

Middleton, A ^{[1
]}

Monkman, AP ^{[1
]}

机构：

[1] UNIV LEEDS,IRC POLYMER SCI & TECHNOL,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

SYNTHETIC METALS | 1997年 / 84卷 / 1-3期

关键词：

polyaniline synthesis; solution processing; conductivity;

D O I：

10.1016/S0379-6779(96)03836-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Aniline was polymerised at temperatures of between 0 and -35 degrees C in acid solution containing lithium chloride and using dichromate oxidant. The optimum temperature to give high molecular weight polyaniline in the emeraldine oxidation state in good yield was found to be -22 +/- 3 degrees C. A solvent cast polyaniline camphorsulfonate film was uniaxially stressed to give a conductivity of 848 +/- 70 Scm(-1) along the stretch direction and 118 +/- 10 Scm(-1) perpendicular to this.

引用

页码：61 / 62

页数：2

共 7 条

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