Reaction between the (3,1) isomer of Ru2(F5ap)4Cl and CN-.: Synthesis, structural determination, and electrochemistry of Ru2(F5ap)3[μ-(o-NC)F4ap](μ-CN) and two geometric isomers of Ru2(F5ap)4(μ-CN)2

被引：15

作者：

Bear, JL ^{[1
]}

Li, YL ^{[1
]}

Cui, J ^{[1
]}

Han, BC ^{[1
]}

Van Caemelbecke, E ^{[1
]}

Phan, T ^{[1
]}

Kadish, KM ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 04期

关键词：

D O I：

10.1021/ic990100+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, structure, and electrochemical properties of three diruthenium complexes represented as Ru-2(F(5)ap)(3)[mu-(o-NC)F(4)ap](mu-CN) and Ru-2(F(5)ap)(4)(mu-CN)(2) (two isomers) are reported. Ru-2(F(5)ap)(3)[mu-(o-NC)F(4)ap](mu-CN), which is proposed to contain a Ru-2(5+) core, undergoes two one-electron oxidations and a single one-electron reduction while the two isomers of Ru-2(F(5)ap)(4)(mu-CN)(2) undergo two one-electron reductions and a single one-electron oxidation.

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页码：857 / +

页数：6

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