Photocatalytic and photochemical degradation of nitrobenzene using artificial ultraviolet light

被引：100

作者：

Bhatkhande, DS ^{[1
]}

Kamble, SP ^{[1
]}

Sawant, SB ^{[1
]}

Pangarkar, VG ^{[1
]}

机构：

[1] Univ Bombay, Inst Chem Technol, Div Chem Engn, Bombay 400019, Maharashtra, India

来源：

CHEMICAL ENGINEERING JOURNAL | 2004年 / 102卷 / 03期

关键词：

nitrobenzene; TiO2; phenol; UV light; photocatalysis; H2O2;

D O I：

10.1016/j.cej.2004.05.009

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Photocatalytic degradation of nitrobenzene has been studied using a semiconductor as photocatalyst and an artificial UV source. The effect of catalyst loading, pH and anions on the photocatalytic degradation of nitrobenzene has been investigated. A kinetic model for the photocatalytic process was investigated. Two types of commercial catalysts Degussa P-25 and Aldrich-TiO2 (anatase TiO2 having surface area 250 m(2) g(-1)) have been compared. Also the degradation has been studied using two different lamps of different A comparison of photocatalytic degradation of nitrobenzene with phenol showed that nitrobenzene degrades more rapidly than phenol. Further, photochemical degradation of nitrobenzene using hydrogen peroxide and artificial UV lamp has been studied and found to be inferior to the photocatalytic degradation. (C) 2004 Elsevier B.V All rights reserved.

引用

页码：283 / 290

页数：8

共 35 条

[1] EFFECTS OF COMMON INORGANIC ANIONS ON RATES OF PHOTOCATALYTIC OXIDATION OF ORGANIC-CARBON OVER ILLUMINATED TITANIUM-DIOXIDE [J].

ABDULLAH, M ;

LOW, GKC ;

MATTHEWS, RW .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (17) :6820-6825

[2]

Adkins R.L., 1994, KIRK OTHMER ENCY CHE, P133

[3]

Ajmera AA, 2002, CHEM ENG TECHNOL, V25, P173, DOI 10.1002/1521-4125(200202)25:2<173::AID-CEAT173>3.0.CO

[4]

2-C

[5]

Beenackers A. A., 2000, CLEAN PRODUCTS PROCE, V2, P149, DOI DOI 10.1007/S100980000080

[6] Photocatalytic degradation of chlorobenzene using solar and artificial UV radiation [J].

Bhatkhande, DS ;

Sawant, SB ;

Schouten, JC ;

Pangarkar, VG .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2004, 79 (04) :354-360

[7] Photocatalytic degradation of nitrobenzene using titanium dioxide and concentrated solar radiation: chemical effects and scaleup [J].

Bhatkhande, DS ;

Pangarkar, VG ;

Beenackers, AACM .

WATER RESEARCH, 2003, 37 (06) :1223-1230

[8] Photocatalytic degradation for environmental applications - a review [J].

Bhatkhande, DS ;

Pangarkar, VG ;

Beenackers, AACM .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2002, 77 (01) :102-116

[9] Photocatalytic transformation of organic compounds in the presence of inorganic ions [J].

Calza, P ;

Pelizzetti, E .

PURE AND APPLIED CHEMISTRY, 2001, 73 (12) :1839-1848

[10] Reaction engineering of suspended solid heterogeneous photocatalytic reactors [J].

Cassano, AE ;

Alfano, OM .

CATALYSIS TODAY, 2000, 58 (2-3) :167-197

← 1 2 3 4 →