A robust porous material constructed of linear coordination polymer chains: Reversible single-crystal to single-crystal transformations upon dehydration and rehydration

被引：375

作者：

Lee, EY ^{[1
]}

Suh, MP ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Mol Engn, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 21期

关键词：

adsorption; coordination polymers; host-guest systems; microporous materials; nickel;

D O I：

10.1002/anie.200353494

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hole in one: A metal-organic framework with permanent microporosity has been constructed from linear coordination polymer chains consisting of Ni(cyclam)]2+ and bpydc2-. In framework 1 the chains run in three directions (red, green, blue in the picture) and are stacked to form 1D channels that are filled with water molecules, which can be removed completely and reabsorbed with retention of the single crystallinity.

引用

页码：2798 / 2801

页数：4

共 50 条

[1] Supramolecular isomerism in coordination compounds: Nanoscale molecular hexagons and chains
Abourahma, H
Moulton, B
Kravtsov, V
Zaworotko, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) : 9990 - 9991
[2] Organoplatinum crystals for gas-triggered switches
Albrecht, M
Lutz, M
Spek, AL
van Koten, G
[J]. NATURE, 2000, 406 (6799) : 970 - 974
[3] ATKINS PW, 1990, PHYSICAL CHEM, P885
[4] Cyano-bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) framework materials:: Versatile solid chemical sensors
Beauvais, LG
Shores, MP
Long, JR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) : 2763 - 2772
[5] Channel-containing 1D coordination polymers based on a linear dimetallic spacer
Belcher, WJ
Longstaff, CA
Neckenig, MR
Steed, JW
[J]. CHEMICAL COMMUNICATIONS, 2002, (15) : 1602 - 1603
[6] Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO
[7] 2-#
[8] BIRADHA K, 2000, ANGEW CHEM, V112, P4001
[9] Breck D.W, 1974, ZEOLITE MOL SIEVES
[10] Cu2(ATC)•6H2O:: Design of open metal sites in porous metal-organic crystals (ATC:1,3,5,7-adamantane tetracarboxylate)
Chen, BL
Eddaoudi, M
Reineke, TM
Kampf, JW
O'Keeffe, M
Yaghi, OM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) : 11559 - 11560

← 1 2 3 4 5 →