Electrically conductive copolymers based on 1-methylpyrrole

被引:9
作者
Geissler, U [1 ]
Hallensleben, ML [1 ]
Rohde, N [1 ]
机构
[1] UNIV HANNOVER,INST MAKROMOL CHEM,D-30167 HANNOVER,GERMANY
关键词
photoluminescence; Raman spectroscopy; polypyrrole and derivatives;
D O I
10.1016/S0379-6779(97)80699-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The fluorescence and Raman spectra of bis(1-methylpyrrol-2-yl)arene derivatives are reported in order to obtain information about the conjugation in poly(bis-1-methylpyrrolylene-alt-arylene)s. The luminescence and the frequency dispersion were influenced by electronic effects and steric demands. Photo polymerization is observed during light irradiation. This effect is most pronounced in case of the 2,5-bis(1-methylpyrrol-2-yl)furan.
引用
收藏
页码:173 / 174
页数:2
相关论文
共 11 条
[1]  
Bredas J. L., 1991, CONJUGATED POLYM
[2]   Poly{arylene-alt-[bis(1-methylpyrrolylene)]}s .1. Synthesis and electrochemical polymerization of terarenes [J].
Geissler, U ;
Hallensleben, ML ;
Rohde, N .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (08) :2565-2576
[3]  
GEISSLER U, UNPUB
[4]   FLEXIBLE LIGHT-EMITTING-DIODES MADE FROM SOLUBLE CONDUCTING POLYMERS [J].
GUSTAFSSON, G ;
CAO, Y ;
TREACY, GM ;
KLAVETTER, F ;
COLANERI, N ;
HEEGER, AJ .
NATURE, 1992, 357 (6378) :477-479
[5]   SOLUBLE CONDUCTING POLYPYRROLE - POLY(3-OCTYLPYRROLE) [J].
MASUDA, H ;
TANAKA, S ;
KAERIYAMA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (11) :725-726
[6]   SELF-SENSITIZED PHOTOPOLYMERIZATION OF PYRROLE [J].
RODRIGUEZ, I ;
GONZALEZVELASCO, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (05) :387-388
[7]   REPEAT UNIT SYMMETRY EFFECTS ON THE PHYSICAL AND ELECTRONIC-PROPERTIES OF PROCESSABLE, ELECTRICALLY CONDUCTING, SUBSTITUTED POLY(1,4-BIS(2-THIENYL)PHENYLENES) [J].
RUIZ, JP ;
DHARIA, JR ;
REYNOLDS, JR ;
BUCKLEY, LJ .
MACROMOLECULES, 1992, 25 (02) :849-860
[8]  
Skotheim T.A., 1986, HDB CONDUCTING POLYM
[9]   Poly[bis(pyrrol-2-yl)arylenes]: Conducting polymers from low oxidation potential monomeps based on pyrrole via electropolymerization [J].
Sotzing, GA ;
Reynolds, JR ;
Katritzky, AR ;
Soloducho, J ;
Belyakov, S ;
Musgrave, R .
MACROMOLECULES, 1996, 29 (05) :1679-1684
[10]  
THEMANS B, 1989, SYNTHETIC MET, V28, pC359, DOI 10.1016/0379-6779(89)90546-8